Technically all boilers can work with a multi zone system. You just have to check whether your boiler is on/off or opentherm compatible. You can do this by looking up your boiler in our connection table (only available in Dutch).
When ordering a Tado thermostat, there's only one version. You either connect it to the on/off or opentherm connection in your boiler, and the rest is software related.
When ordering Evohome, you must know up front, as it either comes with an on/off relay or opentherm relay.